Superoleophobic surfaces are of interest for anti-fouling, self-cleaning, anti-smudge, low-drag, anti-fog, and oil-water separation applications. Current bioinspired surfaces are of limited use due to a lack of mechanical durability. A so-called layer-by-layer approach, involving charged species with electrostatic interactions between layers, can provide the flexibility needed to improve adhesion to the substrate while providing a low surface tension coating at the air interface. In this work, a polyelectrolyte binder, SiO2 nanoparticles, and a fluorosurfactant are spray deposited separately to create a durable, superoleophobic coating. Polydiallyldimethylammonium chloride (PDDA) polyelectrolyte was complexed with a fluorosurfactant layer (FL), which provides oil repellency while being hydrophilic. This oleophobic/superhydrophilic behavior was enhanced through the use of roughening with SiO2 particles resulting in a superoleophobic coating with hexadecane contact angles exceeding 155° and tilt angles of less than 4°. The coating is also superhydrophilic, which is desirable for oil-water separation applications. The durability of these coatings was examined through the use of micro- and macrowear experiments. These coatings currently display characteristics of transparency. Fabrication of these coatings via the layer-by-layer technique results in superoleophobic surfaces displaying improved durability compared to existing work where either the durability or the oil-repellency is compromised.
The coating of thin films is applied in numerous fields and many methods are employed for the deposition of these films. Some coating techniques may deposit films at high speed; for example, ordinary printing paper is coated with micrometre-thick layers of clay at a speed of tens of meters per second. However, to coat nanometre thin films at high speed, vacuum techniques are typically required, which increases the complexity of the process. Here, we report a simple wet chemical method for the high-speed coating of films with thicknesses at the nanometre level. This soap-film coating technique is based on forcing a substrate through a soap film that contains nanomaterials. Molecules and nanomaterials can be deposited at a thickness ranging from less than a monolayer to several layers at speeds up to meters per second. We believe that the soap-film coating method is potentially important for industrial-scale nanotechnology.
Since its discovery, the wetting transparency of graphene, the transmission of the substrate wetting property over graphene coating, has gained significant attention due to its versatility for potential applications. Yet, there have been debates on the interpretation and validity of the wetting transparency. Here, we present a theory taking two previously disregarded factors into account and elucidate the origin of the partial wetting transparency. We show that the liquid bulk modulus is crucial to accurately calculate the van der Waals interactions between the liquid and the surface, and that various wetting states on rough surfaces must be considered to understand a wide range of contact angle measurements that cannot be fitted with a theory considering the flat surface. In addition, we reveal that the wetting characteristic of the substrate almost vanishes when covered by any coating as thick as graphene double layers. Our findings reveal a more complete picture of the wetting transparency of graphene as well as other atomically thin coatings, and can be applied to study various surface engineering problems requiring wettability-tuning.
Smells are known to be composed of thousands of chemicals with various concentrations, and thus, the extraction of specific information from such a complex system is still challenging. Herein, we report for the first time that the nanomechanical sensing combined with machine learning realizes the specific information extraction, e.g. alcohol content quantification as a proof-of-concept, from the smells of liquors. A newly developed nanomechanical sensor platform, a Membrane-type Surface stress Sensor (MSS), was utilized. Each MSS channel was coated with functional nanoparticles, covering diverse analytes. The smells of 35 liquid samples including water, teas, liquors, and water/EtOH mixtures were measured using the functionalized MSS array. We selected characteristic features from the measured responses and kernel ridge regression was used to predict the alcohol content of the samples, resulting in successful alcohol content quantification. Moreover, the present approach provided a guideline to improve the quantification accuracy; hydrophobic coating materials worked more effectively than hydrophilic ones. On the basis of the guideline, we experimentally demonstrated that additional materials, such as hydrophobic polymers, led to much better prediction accuracy. The applicability of this data-driven nanomechanical sensing is not limited to the alcohol content quantification but to various fields including food, security, environment, and medicine.
Analysis of a radioactive, coated concrete core from the decommissioned, spent nuclear fuel cooling pond at the Hunterston-A nuclear site (UK) has provided a unique opportunity to study radionuclides within a real-world system. The core, obtained from a dividing wall and sampled at the fill level of the pond, exhibited radioactivity (dominantly (137)Cs and (90)Sr) heterogeneously distributed across both painted faces. Chemical analysis of the core was undertaken using microfocus spectroscopy at Diamond Light Source, UK. Mapping of Sr across the surface coatings using microfocus X-ray fluorescence (μXRF) combined with X-ray absorption spectroscopy showed that Sr was bound to TiO2 particles in the paint layers, suggesting an association between TiO2 and radiostrontium. Stable Sr and Cs sorption experiments using concrete coupons were also undertaken to assess their interactions with the bulk concrete in case of a breach in the coating layers. μXRF and scanning electron microscopy showed that Sr was immobilized by the cement phases, whilst at the elevated experimental concentrations, Cs was associated with clay minerals in the aggregates. This study provides a crucial insight into poorly understood infrastructural contamination in complex systems and is directly applicable to the UK’s nuclear decommissioning efforts.
Flame-retardant and self-healing superhydrophobic coatings are fabricated on cotton fabrics by a convenient solution dipping method, which involves the sequential deposition of a trilayer of branched poly(ethylenimine) (bPEI), ammonium polyphosphate (APP) and fluorinated-decyl polyhedral oligomeric silsequioxane (F-POSS). When directly exposed to flame, such a trilayer coating generates a porous char layer because of its intumescent effect, successfully endowing the coated fabric with self-extinguishing property. Meanwhile, the preserved F-POSS in cotton fabrics and APP/bPEI coating produce a superhydrohobic surface with self-healing function. The coating can repetitively and autonomically restore superhydrophobicity once the superhydrophobicity is damaged. The resultant cotton fabrics, which are flame resistant, waterproof and self-cleaning, can be readily cleaned with simple water rinsing. Thus, the integration of self-healing superhydrophobicity with flame-retardancy provides a practical way to solve the problem regarding the washing durability of the flame-retardant coatings. The flame-retardant and superhydrophobic fabrics can endure more than 1000 cycles of abrasion under a pressure of 44.8 kPa without losing its flame-retardancy and self-healing superhydrophobicity, showing potential applications as multifunctional advanced textiles.
Electrochemical deposition and evaluation of electrically conductive polymer coating on biodegradable magnesium implants for neural applications
- Journal of materials science. Materials in medicine
- Published over 5 years ago
In an attempt to develop biodegradable, mechanically strong, biocompatible, and conductive nerve guidance conduits, pure magnesium (Mg) was used as the biodegradable substrate material to provide strength while the conductive polymer, poly(3,4-ethylenedioxythiophene) (PEDOT) was used as a conductive coating material to control Mg degradation and improve cytocompatibility of Mg substrates. This study explored a series of electrochemical deposition conditions to produce a uniform, consistent PEDOT coating on large three-dimensional Mg samples. A concentration of 1 M 3,4-ethylenedioxythiophene in ionic liquid was sufficient for coating Mg samples with a size of 5 × 5 × 0.25 mm. Both cyclic voltammetry (CV) and chronoamperometry coating methods produced adequate coverage and uniform PEDOT coating. Low-cost stainless steel and copper electrodes can be used to deposit PEDOT coatings as effectively as platinum and silver/silver chloride electrodes. Five cycles of CV with the potential ranging from -0.5 to 2.0 V for 200 s per cycle were used to produce consistent coatings for further evaluation. Scanning electron micrographs showed the micro-porous structure of PEDOT coatings. Energy dispersive X-ray spectroscopy showed the peaks of sulfur, carbon, and oxygen, indicating sufficient PEDOT coating. Adhesion strength of the coating was measured using the tape test following the ASTM-D 3359 standard. The adhesion strength of PEDOT coating was within the classifications of 3B to 4B. Tafel tests of the PEDOT coated Mg showed a corrosion current (I(CORR)) of 6.14 × 10(-5) A as compared with I(CORR) of 9.08 × 10(-4) A for non-coated Mg. The calculated corrosion rate for the PEDOT coated Mg was 2.64 mm/year, much slower than 38.98 mm/year for the non-coated Mg.
The aim of this study is to prepare whey protein (WP)-based microparticles (MP) using the Encapsulator(®) device. The viscosity dependence of the extrusion device required to mix WP with a food-grade and less viscous polymer. Mixed WP/ALG MP were obtained with the optimized WP/alginate (ALG) ratio (62/38). These particles were further coated with WP or ALG using non-traumatic and solvent-free coating process developed in this study. Size and morphology of coated and uncoated MP were determined. Then, swelling and degradation (WP release) of formulations were investigated in pH 1.2 and 7.5 buffers and in simulated gastric and intestinal fluids (SGF, SIF) and compared to pure ALG and pure WP particle behaviours. At pH 1.2, pure ALG shrank and pure WP swelled, whereas the sizes of mixed WP/ALG matrix were stable. In SGF, WP/ALG MP resisted to pepsin degradation compare to pure WP particles due to ALG shrinkage which limited pepsin diffusion within particles. Coating addition with WP or ALG slowed down pepsin degradation. At pH 7.5, WP/ALG particles were rapidly degraded due to ALG sensitivity but the addition of a WP coating limited effectively the swelling and the degradation of MP. In SIF, pancreatin accelerated MP degradation but ALG-coated MP exhibited interesting robustness. These results confirmed the interest and the feasibility to produce coated WP-based MP which could be a potential orally controlled release drug delivery system.
AIM: The first aim of the present experiment was to compare bone healing at implants installed in recipient sites prepared with conventional drills or a piezoelectric device. The second aim was to compare implant osseointegration onto surfaces with and without dendrimers coatings. MATERIAL AND METHODS: Six Beagles dogs were used in this study. Five implants with two different surfaces, three with a ZirTi(®) surface (zirconia sand blasted, acid etched), and two with a ZirTi(®) -modified surface with dendrimers of phosphoserine and polylysine were installed in the right side of the mandible. In the most anterior region (P2, P3), two recipient sites were prepared with drills, and one implant ZirTi(®) surface and one coated with dendrimers implants were installed at random. In the posterior region (P4 and M1), three recipient sites were randomly prepared: two sites with a Piezosurgery(®) instrument and one site with drill and two ZirTi(®) surface and one coated with dendrimers implants installed. Three months after the surgery, the animals were sacrificed for histological analysis. RESULTS: No complications occurred during the healing period. Three implants were found not integrated and were excluded from analysis. However, n = 6 was obtained. The distance IS-B at the buccal aspect was 2.2 ± 0.8 and 1.8 ± 0.5 mm, while IS-C was 1.5 ± 0.9 and 1.4 ± 0.6 mm at the Piezosurgery(®) and drill groups, respectively. Similar values were obtained between the dendrimers-coated and ZirTi(®) surface implants. The BIC% values were higher at the drill (72%) compared to the Piezosurgery(®) (67%) sites. The BIC% were also found to be higher at the ZirTi(®) (74%) compared to the dendrimers-coated (65%) implants, the difference being statistically significant. CONCLUSION: This study has revealed that oral implants may osseointegrate equally well irrespective of whether their bed was prepared utilizing conventional drills with abundant cooling or Piezosurgery(®) . Moreover, the surface coating of implants with dendrimers phosphoserine and polylysine did not improve osseointegration.
- Langmuir : the ACS journal of surfaces and colloids
- Published over 5 years ago
Long lasting anticorrosive coatings for steel have been developed based on halloysite nanotubes loaded with three corrosion inhibitors: benzotriazole, mercaptobenzothiazole and mercaptobenzimidazole. The inhibitors' loaded tubes were admixed at 5-10 wt % to oil based alkyd paint providing sustained agent release and corrosion healing in the coating defects. Slow 20-30 hour release of the inhibitors in defect points caused remarkable improvement in anticorrosion efficiency of the coatings. Further time expansion of anticorrosion agents release has been achieved by formation of release stoppers at nanotube-ends with urea-formaldehyde copolymer and copper-inhibitor complexation. Corrosion protection efficiency was tested on ASTM A366 steel plates in 0.5 M NaCl solution with microscanning of corrosion current development, by microscopy inspection and studying paint adhesion. The best protection was found using halloysite / mercaptobenzimidazole and benzotriazole inhibitors. Stopper formation with urea-formaldehyde copolymer provided additional increase in corrosion efficiency due to longer release of inhibitors.