Microstructures and mechanical performance of polyelectrolyte/nanocrystalline TiO2 nanolayered composites
OPEN Nanoscale research letters | 23 Jan 2013
B Zhang, HF Tan, JW Yan, MD Zhang, XD Sun and GP Zhang
Biological materials with hierarchically laminated structures usually exhibit a good synergy between strength and fracture toughness. Here, we show that a bio-inspired (polyelectrolyte (PE)/TiO2)4 nanolayered composite with a thickness ratio of TiO2 and amorphous PE layers of about 1.1 has been prepared successfully on Si substrates by layer-by-layer self-assembly and chemical bath deposition methods. Microstructures of the nanolayered composite were investigated by scanning electron microscopy, secondary ion mass spectroscopy, and high-resolution transmission microscopy. Mechanical performance of the composite was characterized by instrumented indentation. The composite consisting of 17.9-nm-thick nanocrystalline TiO2 and 16.4-nm-thick amorphous PE layers has a strength of about 245 MPa, which is close to that of shells, while the fracture toughness of the composite, KIC = 1.62 +/- 0.30 MPa . m1/2, is evidently higher than that of the bulk TiO2. A possible strategy to build the composite at nanoscale for high mechanical performance was addressed.
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